Benzyl chloroformate 50 in toluene msds pdf

Import data and price of benzyl chloroformate under hs. Benzylchloroformate 50% solution in toluene, 501531, laboratory chemicals, c8h7clo2 by loba chemie, india. Benzyl chloroformate 501531 msds report, benzyl chloroformate msds safety technical specifications search, benzyl chloroformate safety information specifications ect. Floreancig department of chemistry university of pittsburgh pittsburgh, pennsylvania 15260, usa general experimental. Polyethylene is susceptible to attack by some chemicals which may cause stress cracking, swelling, oxidation or may permeate the polyethylene. Benzyl chloroformate solution technical, 50 % in toluene synonym.

The substance identity section is calculated from substance identification information from all echa databases. On this page you will be able to access individual acute exposure guideline level aegls values that are intended to protect most individuals in the general population, including those that might be particularly susceptible to the harmful effects of the chemicals. Safety data sheet according to federal register vol. Nontoxic in contact with skin ld50 skin 5000 mg kg. Control parameters sampling time update methyl mercaptan 74931 methemoglobin. Benzyl chloroformate 501531 msds, safety technical. Benzyl chloroformate decomposes slowly in water forming benzyl alcohol, hcl, and co2. Attach the empty distilling column as an air condenser. Monobenzylation to benzyltoluenes is the main reaction, usually higher than 90% selectivity when a toluenebenzyl chloride molar ratio of 5 is used.

Benzyl chloroformate market research report forecast to. Benzyl chloroformate 50 % in toluene a colourless to lightyellow liquid that is used as an intermediate in apis. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. After cooling, the colorless crystalline solid was isolated by filtration, washed with cold toluene, and recrystallized from ethanol. Benzyl chloroformate also known as benzyloxycarbonyl chloride, benzyl chlorocarbonate, carbobenzoxy chloride, carbonochloridic acid phenylmethyl ester, and zchloride, and represent with the linear formula clco2ch2c6h5, which is a clear light oily liquid, and variants its color to yellow to colorless, although it is also known for its pungent odor. Articles of benzyl 1cyano1 methylethylcarbamate are included as well. Benzyl chloroformate solution technical, 50% in toluene sigma. Extra dry solvents deuterated solvents organometallic. R e f e r e n c e i n f o r m a t i o n threshold limit values tlv and immediately dangerous to life and health idlh values. It is a colorless, water insoluble liquid with the smell associated with paint thinners. Benzyl chloroformate 501531 buy and find out price and availability, msds, properties of. Precautionary statements p210 keep away from heat, hot surfaces, sparks, open flames and other.

Access acute exposure guideline levels aegls values. Synonym, chloroformic acid benzyl ester 3035% in toluene. Wear suitable protective clothing, gloves and eyeface protection. Pictogram signal word danger hazard statements h224 extremely flammable liquid and vapour. Benzyl chloroformate is a lachrymator that can cause serious damage to eyes and skin on contact. The 2016 emergency response guidebook, developed jointly by transport canada tc, the u. Benzyl chloroformate is the benzyl ester of chloroformic acid. Toluene also known as toluol is an aromatic hydrocarbon.

Firstaid measures general advice show this safety data sheet to the doctor in attendance. It is useful for the introduction of carboxybenzyl cbz protecting group for amines such as aniline in organic synthesis. Benzyl chloroformate solution technical, 50% in toluene. Special hazards arising from the substance or mixture. Benzyl alcohol wikimili, the best wikipedia reader. To estimate kinetic parameters for toluene reaction with benzyl alcohol. The compound can be viewed as the ester of carbamic acid ocohnh 2 and benzyl alcohol, although it is produced from benzyl chloroformate with ammonia. How is benzyl alcohol prepared from toluene oxidation. Ascabin ascabiol benylate benzyl alcohol benzoic ester benzyl benzenecarboxylate. Benzyl acetate suppliers, with sds msds, usa canada europe. Diethyl ether material safety data sheet cas no 6029. Benzylchloroformate 50 % solution in toluene, 501531, laboratory chemicals, c8h7clo2 by loba chemie, india.

Benzyl chloroformate, 50 wt% solution in toluene catalog numbers. Reflux the resulting mixture for 1 h or more, then cool it to room temperature. Benzyl chloroformate 501531 tokyo chemical industry co. Structure, properties, spectra, suppliers and links for. Benzyl chloroformate is widely used as a reactive chemical intermediate in plastic, pharmaceutical, agricultural and organic chemicals. When discolored phosgene was used probably containing iron salts from corrosion of the cylinder, a violent explosion occurred during the distillation phase, presumably. We develop, produce and distribute high quality pharmaceutical chemicals, special chemicals and other fine chemicals.

Benzyl alcohol prepared from toluene by heating it with kmno4 and na2co3 in aqu. View detailed import data, price, monthly trends, major importing countries, major ports of benzyl chloroformate under hs code 2915. A colourless to lightyellow liquid that is used as an intermediate in apis. Benzyl chloroformate c8h7clo2 cid 10387 structure, chemical names, physical and chemical. Loosen clothing and place exposed in a comfortable position. Benzyl chloroformate, 3m 50 wt% solution in toluene bzcf. Inhalation is very harmful to the upper respiratory tract and lungs, and may be fatal if exposure is sufficient. Alkoxy carbamate synthesis and stimulusresponsive alcohol release r. It is a white solid that is soluble in organic solvents and moderately soluble in water. Firstaid measures eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Toluene 108883 50 benzyl chloroformate 501531 50 benzyl chloride 100447 0.

Benzyl acetate is an organic compound with the molecular formula c 9 h 10 o 2. Benzyl carbamate is the organic compound with the formula c 6 h 5 ch 2 oconh 2. Benzyl chloroformate 50% solution in toluene 501531. Methyl mercaptan 74931 immediately dangerous to life or health concentration value 150 parts per million 19950301 us substance name casno. Synthesis of benzyl acetate to a reaction tube add 540 mg of benzyl alcohol and 510 mg of acetic anhydride and a boiling chip. Lot and batch numbers can be found on a products label following the words lot or batch. Identification of the substancemixture and of the companyundertaking. It is a mono substituted benzene derivative, consisting of a ch3 group attached to a phenyl group. In case of accident or if you feel unwell, seek medical advice immediately show the label where possible. It is prepared in the lab by treating benzyl alcohol with phosgene. The benzylation of toluene with benzyl chloride was studied at 383 k in the liquid phase on different protonic zeolites. Benzyl chloroformate cbzcl 1a was introduced by bergmann and zervas about 70 years ago for a nprotective reagent for amino group in peptide synthesis.

Attacks many metals especially in humid atmosphere handling chemicals safely 1980. Benzyl chloroformate, 3m 50 wt% solution in toluene 100ml 42890 benzyl chloroformate, technical grade, 97% 100ml 43077 800ml 430778000 benzylmagnesium chloride, 1. The contributions to this document on benzyl chloride by niosh stafl. Material safety data sheet benzyl chloride msds finar limited. This listing was prepared to provide guidance to the chemical compatibility molded polyethylene. Compatibility chemical compatibility chemicial compatibility guide the following information is intended to be used as a general guideline for pump material selection. Benzylation of toluene by benzyl chloride over protonic. Call a physician or poison control center immediately. Safety data sheet according to 29cfr19101200 and ghs rev. Benzyl acetate is also known as acetic acid, benzyl ester, acetic acid. Also used in a recently reported 3step synthesis of 1,2,4oxadiazoles. A list of common conditions for cbz protection and deprotection in organic chemistry. In case of fire, smoke and other combustion products carbon monoxide, carbon dioxide and benzyl chloride may be formed, the inhalation of such combustion products.

Benzylcarbonyl chloride benzyl chlorocarbonate carbobenzoxy chloride chloroformic acid, benzyl ester restrict access. Also known as benzyl chlorocarbonate it is an oily colorless liquid although impure samples appear yellow. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Nonphosgene synthesis of benzyl chloroformate cbzcl.